Throughout history, cementing materials have played a vital role and were used widely in the ancient world. The Egyptians used calcined gypsum as a cement and the Greeks and Romans used lime made by heating limestone and added sand to make mortar, with coarser stones for concrete.
The Romans found that a cement could be made which set under water and this was used for the construction of harbours. This cement was made by adding crushed volcanic ash to lime and was later called a "pozzolanic" cement, named after the village of Pozzuoli near Vesuvius.
In places where volcanic ash was scarce, such as Britain, crushed brick or tile was used instead. The Romans were therefore probably the first to manipulate systematically the properties of cementitious materials for specific applications and situations.
Marcus Vitruvius Pollio, a Roman architect and engineer in the 1st century BCE wrote his "Ten books of Architecture" - a revealing historical insight into ancient technology. Writing about concrete floors, for example:
"First I shall begin with the concrete flooring, which is the most important of the polished finishings, observing that great pains and the utmost precaution must be taken to ensure its durability".
"On this, lay the nucleus, consisting of pounded tile mixed with lime in the proportions of three parts to one, and forming a layer not less than six digits thick."
And on pozzolana:
"There is also a kind of powder from which natural causes produces astonishing results. This substance, when mixed with lime and rubble, not only lends strength to buildings of other kinds, but even when piers are constructed of it in the sea, they set hard under water."
(Vitruvius, "The Ten Books of Architecture," Dover Publications, 1960.)
His "Ten books of Architecture" are a real historical gem bringing together history and technology. Anyone wishing to follow his instructions might first need to find a thousand or so slaves to dig, saw, pound and polish...
After the Romans, there was a general loss in building skills in Europe, particularly with regard to cement. Mortars hardened mainly by carbonation of lime, a slow process. The use of pozzolana was rediscovered in the late Middle Ages.
The great mediaeval cathedrals, such as Durham, Lincoln and Rochester in England and Chartres and Rheims in France, were clearly built by highly skilled masons. Despite this, it would probably be fair to say they did not have the technology to manipulate the properties of cementitious materials in the way the Romans had done a thousand years earlier.
The Renaissance and Age of Enlightenment brought new ways of thinking which led to the industrial revolution. In eighteenth century Britain, the interests of industry and empire coincided, with the need to build lighthouses on exposed rocks to prevent shipping losses. The constant loss of merchant ships and warships drove cement technology forwards.
Smeaton, building the third Eddystone lighthouse (1759) off the coast of
Cornwall in Southwestern England, found that a mix of lime, clay and
crushed slag from iron-making produced a mortar which hardened under
water. Joseph Aspdin took out a patent in 1824 for "Portland Cement," a
material he produced by firing finely-ground clay and limestone until
the limestone was calcined. He called it Portland Cement because the
concrete made from it looked like Portland stone, a widely-used building
stone in England.
While history usually regards Aspdin as the inventor of Portland cement, Aspdin's cement was not produced at a high-enough temperature to be the real forerunner of modern Portland cement. Nevertheless, his was a major innovation and subsequent progress could be viewed as mere development.
A ship carrying barrels of Aspdin's cement sank off the Isle of Sheppey in Kent, England, and the barrels of set cement, minus the wooden staves, were later incorporated into a pub in Sheerness and are still there now. Those who wish can sup a pint and contemplate cement history!
A few years later, in 1845, Isaac Johnson made the first modern Portland Cement by firing a mixture of chalk and clay at much higher temperatures, similar to those used today. At these temperatures (1400C-1500C), clinkering occurs and minerals form which are very reactive and more strongly cementitious.
While Johnson used the same materials to make Portland cement as we use now, three important developments in the manufacturing process lead to modern Portland cement:
From the turn of the 20th century, rotary
cement kilns gradually replaced the original vertical shaft kilns, used originally for
making lime. Rotary kilns heat the clinker mainly by
radiative heat transfer and this is more efficient at higher
temperatures, enabling higher burning temperatures to be achieved. Also,
because the clinker is constantly moving within the kiln, a fairly
uniform clinkering temperature is achieved in the hottest part of the
kiln, the burning zone.
The two other principal technical developments, gypsum addition to control setting and the use of ball mills to grind the clinker, were also introduced at around the start of the 20th century.
An entire website could easily be devoted to the history of cement, but this brief introduction may suffice to place cement in a historical context.
Articles like this one can provide a lot of useful material. However, reading an article or two is not really the best way to get a clear picture of a complex material like cement. To get a more complete and integrated understanding of cement and concrete, do have a look at the Understanding Cement book or ebook.
This easy-to-read and concise book contains much more detail on concrete chemistry and deleterious processes in concrete compared with the website.
For example, it has about two-and-a-half times as much on ASR, one-and-a-half times as much on sulfate attack and nearly three times as much on carbonation. It has sections on alkali-carbonate reaction, frost (freeze-thaw) damage, steel corrosion, leaching and efflorescence on masonry. It also has about four-and-a-half times as much on cement hydration (comparisons based on word count).
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