Alkali-silica reaction (ASR) can cause serious expansion and cracking in concrete, resulting in major structural problems and sometimes necessitating demolition. This is a short introduction to ASR - for more information, see the Understanding Cement book/ebook.
ASR is the most common form of alkali-aggregate reaction (AAR) in concrete; the other, much less common, form is alkali-carbonate reaction (ACR). ASR and ACR are therefore both subsets of AAR.
caused by a reaction between the hydroxyl ions in the alkaline cement
pore solution in the concrete and reactive forms of silica in the
aggregate (eg: chert, quartzite, opal, strained quartz crystals).
A gel is produced, which increases in volume by taking up water and so exerts an expansive pressure, resulting in failure of the concrete. In unrestrained concrete (that is, without any reinforcement), ASR causes characteristic 'map cracking' or 'Isle of Man cracking'.
Gel may be present in cracks and within aggregate particles. The best technique for the identification of ASR is the examination of concrete in thin section, using a petrographic microscope. Alternatively, polished sections of concrete can be examined by scanning electron microscopy (SEM); this has the advantage that the gel can be analysed using X-ray microanalysis in order to confirm the identification beyond any doubt.
The conditions required for ASR to occur are:
The use of pozzolans in the concrete mix as a partial cement replacement can reduce the likelihood of ASR occurring as they reduce the alkalinity of the pore fluid.
With some aggregates, expansion due to ASR increases in proportion with the amount of reactive aggregate in the concrete. Other aggregates show what is called a “pessimum” effect; if the proportion of reactive aggregate in test mixes is varied, while other factors are kept constant, maximum concrete expansion occurs at a particular aggregate content. Higher or lower proportions of reactive aggregate will give a lower expansion.
The process of ASR is believed to be in many respects similar to the pozzolanic reaction, such as occurs normally in concrete containing pulverised fuel ash (PFA), for example. However, there is an important difference. In the pozzolanic reaction small pozzolanic particles are reacting in a Ca-rich environment, while ASR occurs in mature concrete and involves larger particles of aggregate.
The pozzolanic reaction mechanism is believed to be a process in which silicate anions are detached from the reactive aggregate by hydroxyl ions in the pore fluid. Sodium and potassium ions are the ions most readily-available to balance the silicate anions and an alkali-silicate gel is formed. This can take up (imbibe) water and is mobile. The alkali-silicate gel is unstable in the presence of calcium, and calcium silicate hydrate (C-S-H) is formed.
In the pozzolanic reaction where a pozzolan is used as a partial cement replacement, the particles are small. As there is much calcium available in young concrete, the alkali-silicate gel forms in a thin layer around the pozzolanic particle and quickly converts to C-S-H. No expansion results.
In the case of ASR, the reaction usually occurs much later, possibly years after the concrete was placed. Large aggregate particles (large, that is, compared with cement-sized pozzolan) generate a significant volume of gel which then takes up water and expands within the hardened, mature concrete.
Because the concrete is mature, calcium availability is limited as most of the calcium is bound up in stable solid phases. The rate of supply of calcium is therefore insufficient to convert the gel quickly to C-S-H. Expansion of the gel as water is taken up, may result in damage to the surrounding concrete. Over time, the gel slowly does take up calcium; eventually the composition of the alkali-silica gel may become very similar to that of the calcium silicate hydrate in the cement paste (see Figure 4). By then, though, the damage to the concrete may have already been done.
The composition of the gel extruded from the aggregate changes with time, becoming more similar to the surrounding calcium silicate hydrates. In Figure 4 at a) the gel spectrum shows large peaks due to silicon and potassium (the alkali) and only a very weak peak due to calcium. At b) the calcium peak has become much stronger and the potassium peak much weaker. At c) the potassium peak has disappeared entirely and the gel has approximately the same composition as the normal calcium silicate hydrate comprising the bulk of the cement paste. Clearly, the gel is older with increasing distance from the aggregate particle in which it originated - the 'oldest' gel has had more time in which to take up calcium from the surrounding paste, and has now become calcium silicate hydrate.
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Articles like this one can provide a lot of useful material. However, reading an article or two is not really the best way to get a clear picture of a complex material like cement. To get a more complete and integrated understanding of cement and concrete, do have a look at the Understanding Cement book or ebook.
This easy-to-read and concise book contains much more detail on concrete chemistry and deleterious processes in concrete compared with the website.
For example, it has about two-and-a-half times as much on ASR, one-and-a-half times as much on sulfate attack and nearly three times as much on carbonation. It has sections on alkali-carbonate reaction, frost (freeze-thaw) damage, steel corrosion, leaching and efflorescence on masonry. It also has about four-and-a-half times as much on cement hydration (comparisons based on word count).
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